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Title: | A new two steps synthesis of α-substituted γ-methyl γ-lactones from nitroalkanes |
Authors: | Ballini, Roberto Bosica, Giovanna |
Keywords: | Nitroalkanes -- Synthesis Chemistry, Analytic |
Issue Date: | 1996 |
Publisher: | Georg Thieme Verlag |
Citation: | Ballini, R., & Bosica, G. (1996). A new two steps synthesis of α-substituted γ-methyl γ-lactones from nitroalkanes. Synlett, 11, 1115-1116. |
Abstract: | α-Substituted γ-methyl γ-lactones are efficiently prepared, in two steps, by regiospecific Michael addition of nitroalkanes to methyl trans-4-oxo-2-pentenoate in MeCN/DBU followed by chemoselective reduction of the obtained enones with NiCl2⋅6H2O/NaBH4. By this method a variety of functionalized 3,5-disubstituted butyrolactones can be obtained. |
URI: | https://www.um.edu.mt/library/oar//handle/123456789/24645 |
Appears in Collections: | Scholarly Works - FacSciChe |
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