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https://www.um.edu.mt/library/oar/handle/123456789/113084| Title: | Serinolic amino-s-triazines: iterative synthesis and rotational stereochemistry phenomena as N-substituted derivatives of 2-aminopropane-1,3-diols |
| Authors: | Pintea, Monica Fazekas, Marijana Lameiras, Pedro Cadis, Adrian-Ionut Berghian, Camelia Silaghi-Dumitrescu, Ioan Popa, Flavia Bele, Constantin Ple, Nelly Darabantu, Mircea |
| Keywords: | Amino alcohols Dendrimers Molecules -- Models Nuclear magnetic resonance spectroscopy |
| Issue Date: | 2008 |
| Publisher: | Elsevier Ltd |
| Citation: | Pintea, M., Fazekas, M., Lameiras, P., Cadis, I., Berghian, C., Silaghi-Dumitrescu, I., ... & Darabantu, M. (2008). Serinolic amino-s-triazines: iterative synthesis and rotational stereochemistry phenomena as N-substituted derivatives of 2-aminopropane-1, 3-diols. Tetrahedron, 64(37), 8851-8870. |
| Abstract: | The iterative synthesis of 2,4,6-triamino-s-triazines (melamines), precursors and dendritic structures, by amination of cyanuric chloride with C-1 versus C-2-substituted 2-aminopropane-1,3-diols (serinols), is comparatively examined. The stereochemistry of the resulting serinolic amino-s-triazines, issued from the restricted rotation about the newly created C(s-triazine)–No bonds, is for the first time discussed in terms of (pro)diastereomerism based on DNMR and DFT calculation data. |
| URI: | https://www.um.edu.mt/library/oar/handle/123456789/113084 |
| Appears in Collections: | Scholarly Works - FacEngMME |
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| Serinolic_amino_s_triazines_iterative_synthesis_and_rotational_stereochemistry_phenomena_as_N_substituted_derivatives_of_2_aminopropane_1_3_diols_2008.pdf Restricted Access | 1.47 MB | Adobe PDF | View/Open Request a copy |
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