1. OAR@UM
  2. Faculty of Science
  3. Department of Chemistry
  4. Scholarly Works - FacSciChe
Please use this identifier to cite or link to this item: https://www.um.edu.mt/library/oar/handle/123456789/24670
Full metadata record
DC FieldValueLanguage
dc.contributor.authorBallini, Roberto-
dc.contributor.authorBosica, Giovanna-
dc.contributor.authorFiorini, Dennis-
dc.contributor.authorGiarlo, Guido-
dc.date.accessioned2017-12-14T10:07:02Z-
dc.date.available2017-12-14T10:07:02Z-
dc.date.issued2001-
dc.identifier.citationBallini, R., Bosica, G., Fiorini, D., & Giarlo, G. (2001). Synthesis of 3-alkyl-2,5-dimethylfuran derivatives by indirect alkylation of 2,5-dimethylfuran with aliphatic nitrocompounds. Synthesis, 13, 2003-2006.en_GB
dc.identifier.urihttps://www.um.edu.mt/library/oar//handle/123456789/24670-
dc.description.abstractThe preparation of 3-alkyl-2,5-dimethylfuranes via indirect alkylation of 2,5-dimethylfuran is reported. Thus, primary nitroalkanes react with cis-3-hexen-2,5-dione giving a tandem Michael addition/elimination of nitrous acid, followed by chemoselective hydrogenation of the C=C double bond of the obtained enones. The Paal-Knorr reaction, performed with p-toluenesulfonic acid in diethyl ether, completes the formation of the title compounds. In this context the nitroalkane can be considered as an alkyl cation synthon.en_GB
dc.language.isoenen_GB
dc.publisherGeorg Thieme Verlagen_GB
dc.rightsinfo:eu-repo/semantics/restrictedAccessen_GB
dc.subjectNitroalkanesen_GB
dc.subjectFuransen_GB
dc.subjectNitro compounds -- Synthesisen_GB
dc.titleSynthesis of 3-alkyl-2,5-dimethylfuran derivatives by indirect alkylation of 2,5-dimethylfuran with aliphatic nitrocompoundsen_GB
dc.typearticleen_GB
dc.rights.holderThe copyright of this work belongs to the author(s)/publisher. The rights of this work are as defined by the appropriate Copyright Legislation or as modified by any successive legislation. Users may access this work and can make use of the information contained in accordance with the Copyright Legislation provided that the author must be properly acknowledged. Further distribution or reproduction in any format is prohibited without the prior permission of the copyright holder.en_GB
dc.description.reviewedpeer-revieweden_GB
dc.identifier.doi10.1055/s-2001-17714-
dc.publication.titleSynthesisen_GB
Appears in Collections:Scholarly Works - FacSciChe

Files in This Item:
File Description SizeFormat 
ballini2001 (7).pdf
  Restricted Access		44.72 kBAdobe PDFView/Open Request a copy
Show simple item record Statistics


Items in OAR@UM are protected by copyright, with all rights reserved, unless otherwise indicated.