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Title: | Michael addition of nitroalkanes to dimethyl citraconate, with DBU as base : an unexpected, one-pot synthesis of polyfunctionalized carbonyl derivatives |
Authors: | Ballini, Roberto Barboni, Luciano Bosica, Giovanna Fiorini, Dennis Gil, Maria Victoria |
Keywords: | Nitroalkanes Ketones Esters Organic compounds |
Issue Date: | 2002 |
Publisher: | Georg Thieme Verlag |
Citation: | Ballini, R., Barboni, L., Bosica, G., Fiorini, D., & Gil, M. V. (2002). Michael addition of nitroalkanes to dimethyl citraconate, with DBU as base : an unexpected, one-pot synthesis of polyfunctionalized carbonyl derivatives. Synlett, 10, 1706-1708. |
Abstract: | Michael addition of nitroalkanes to dimethyl citraconate, with DBU as base, allows the one pot formation of keto diesters. The reaction proceeds through an equilibrium form of the acceptor, followed by Michael addition of the nitroalkane and then, in situ Nef conversion. |
URI: | https://www.um.edu.mt/library/oar//handle/123456789/24874 |
Appears in Collections: | Scholarly Works - FacSciChe |
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