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Please use this identifier to cite or link to this item: https://www.um.edu.mt/library/oar/handle/123456789/24882
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dc.contributor.authorCossu, Sergio-
dc.contributor.authorDe Lucchi, Ottorino-
dc.contributor.authorFabris, Fabrizio-
dc.contributor.authorBallini, Roberto-
dc.contributor.authorBosica, Giovanna-
dc.date.accessioned2017-12-20T08:55:19Z-
dc.date.available2017-12-20T08:55:19Z-
dc.date.issued1996-
dc.identifier.citationCossu, S., De Lucchi, O., Fabris, F., Ballini, R., & Bosica, G. (1996). A Michael route to acetals and thioacetals: preparation of acetals (thioacetals) of 2-sulfonylacetaldehyde from alkynyl and other unsaturated aryl sulfones. Synthesis, 12, 1481-1484.en_GB
dc.identifier.urihttps://www.um.edu.mt/library/oar//handle/123456789/24882-
dc.description.abstractA simple protocol for the direct transformation of arylsulfonylalkynes 1, (Z)- and (E)-1,2-bis(phenylsulfonyl)ethylene (2), and (E)-1-chloro-2-phenylsulfonylethylene (3) into the acetals or thioacetals of acetyl sulfones is presented. It engages the NaH-catalyzed reaction of an alcohol or a thiol with 1-3 at room temperature for 2-12 hours. Emphasis is given to enantiopure C 2 symmetric diols for the production of chiral building blocks to be used in asymmetric synthesis.en_GB
dc.language.isoenen_GB
dc.publisherGeorg Thieme Verlagen_GB
dc.rightsinfo:eu-repo/semantics/restrictedAccessen_GB
dc.subjectNucleophilic reactionsen_GB
dc.subjectAsymmetric synthesisen_GB
dc.titleA Michael route to acetals and thioacetals : preparation of acetals (thioacetals) of 2-sulfonylacetaldehyde from alkynyl and other unsaturated aryl sulfonesen_GB
dc.typearticleen_GB
dc.rights.holderThe copyright of this work belongs to the author(s)/publisher. The rights of this work are as defined by the appropriate Copyright Legislation or as modified by any successive legislation. Users may access this work and can make use of the information contained in accordance with the Copyright Legislation provided that the author must be properly acknowledged. Further distribution or reproduction in any format is prohibited without the prior permission of the copyright holder.en_GB
dc.description.reviewedpeer-revieweden_GB
dc.identifier.doi10.1055/s-1996-4406-
dc.publication.titleSynthesisen_GB
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