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Title: | Fast diastereoselective Baylis–Hillman reaction by nitroalkenes : synthesis of di- and triene derivatives |
Authors: | Ballini, Roberto Barboni, Luciano Bosica, Giovanna Fiorini, Dennis Mignini, Emanuela Palmieri, Alessandro |
Keywords: | Nitroalkanes Nitro compounds Allyl compounds |
Issue Date: | 2004 |
Publisher: | Pergamon Press |
Citation: | Ballini, R., Barboni, L., Bosica, G., Fiorini, D., Mignini, E., & Palmieri, A. (2004). Fast diastereoselective Baylis–Hillman reaction by nitroalkenes : synthesis of di- and triene derivatives. Tetrahedron, 60(23), 4995-4999. |
Abstract: | The Baylis–Hillman reaction is performed using nitroalkenes as activated alkenes, ethyl-2-bromomethylacrylate as electrophilic acceptor and DBU as catalyst base. Nitro dienes are obtained in good yields and very short reaction times. Moreover, starting from appropriate nitroalkenes it is possible to realize one pot the synthesis of trienic systems. |
URI: | https://www.um.edu.mt/library/oar//handle/123456789/24897 |
Appears in Collections: | Scholarly Works - FacSciChe |
Files in This Item:
File | Description | Size | Format | |
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1-s2.0-S0040402004005794-main.pdf Restricted Access | 144.82 kB | Adobe PDF | View/Open Request a copy |
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