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https://www.um.edu.mt/library/oar/handle/123456789/27596| Title: | A new two-step synthesis of 2-alkylated 1, 4-diketones and α-alkylated γ-keto esters |
| Authors: | Ballini, Roberto Bosica, Giovanna Petrelli, Lara Petrini, Marino |
| Keywords: | Chemical reactions Nitroalkanes Chemistry, Organic Nitrous acid |
| Issue Date: | 1999 |
| Publisher: | Thieme Stuttgart |
| Citation: | Ballini, R., Bosica, G., Petrelli, L., & Petrini, M. (1999). A new two-step synthesis of 2-alkylated 1, 4-diketones and α-alkylated γ-keto esters. Synthesis, 1999(07), 1236-1240. |
| Abstract: | 2-Alkylated 1,4-diketones and a-alkylated g-keto esters can be easily prepared by a two-step procedure which involves first the conjugate addition of a nitroalkane to an enedione derivative in acetonitrile with DBU as base, followed by chemoselective hydrogenation of the C–C double bond (H2, 10% Pd/C) of the Michael adduct, obtained after elimination of nitrous acid. |
| URI: | https://www.um.edu.mt/library/oar//handle/123456789/27596 |
| ISSN: | 00397881 |
| Appears in Collections: | Scholarly Works - FacSciChe |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| ballini1999.pdf | 94.25 kB | Adobe PDF | View/Open |
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